2023年1月30日 · In transition metal complexes a change in electron distribution between the metal and a ligand gives rise to charge transfer (CT) bands when performing Ultraviolet-visible …

2021年8月2日 · Here we report that isocyanide chelate ligands give access to air-stable manganese (i) complexes that exhibit MLCT luminescence in solution at room temperature. …

2020年7月13日 · Metal–ligand complexes undergo diverse charge-transfer processes when stimulated by light or electric fields. This Perspective describes how these processes can be …

First, light promotes intramolecular electron transfer (ET) from a coordinating ligand to a metal center, producing a formally reduced metal center and oxidized ligand radical. Second, the …

2023年2月21日 · Transition metal complexes with a metal-centered HOMO and a ligand-based LUMO can have MLCT excited states with lifetimes on the order of nano- to microseconds, …

2024年9月18日 · Ligand-to-metal charge transfer (LMCT) in high-valent metal complexes often triggers bond homolysis, generating oxidized ligand-centered radicals and reduced metal …

2024年11月1日 · This review meticulously examines the charge transfer mechanisms within MOFs upon photoexcitation, with a particular emphasis on ligand-to-metal charge transfer …

2025年1月28日 · Photoinduced metal-to-ligand (or ligand-to-metal) charge-transfer (CT) states in metal complexes have been extensively studied, but primarily limited to CT transitions …

Ligand-to-metal charge transfer (LMCT) excited states are capable of undergoing a wide array of photochemical reactions, yet receive minimal attention compared to other charge transfer …

2 天之前 · This form of emission widely exists and has been extensively investigated in Cu(I) iodide complexes featuring aromatic ligands, which could be ascribed to the radiative …